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7 Elevated Sextant
Divine Orbs are incredibly helpful for Path of exile currency when you finally get your desired unique or rare item only for it to roll some disappointing stats. Before you throw it away, you can risk raising or lowering its stats using the Divine Orb.
Echoes of the Atlas is one of the latest expansions in Path of Exile and it introduced The Maven and along with her, a new currency called the Elevated Sextant. Only she can drop this orb, which is why it's priced at around 56 Chaos Orbs.
The Elevated Sextant, for that matter, is an awesome item capable of buffing several maps in your Atlas just by applying it at a Watchstone. Do use it wisely though and only according to the map's availability.
6 Exalted Orbs
Exalted Orbs now come in many shapes and sizes but they're all similarly priced except for the Warlord, Hunter, and Redeemer variants. For the sake of simplicity, we'd be referring to the basic version of the Exalted Orb, which costs around 120 Chaos Orbs give or take.
Most players hold the Exalted Orb in high regard. Think of it as the 100 dollar bills or Benjies of Path of Exile while the Chaos Orbs are 10s. Most players don't spend them either and only use them to purchase their way into META builds. If you're swimming with them, then you can use them to add a new random property to a rare item.
5 Awakener's Orb 4 Maven's Orb
The Awakener's Orb is a crafter's most prized tool as they can use it to replicate perfect items though the original item will be destroyed. Think of it as a cut-and-paste orb in Path of Exile but for items with influences (Elder, Shaper, etc.).
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As for the price, it's expensive; it costs around 350 Chaos Orbs in Standard at the time of writing. Getting it is also a bit difficult since it only drops from Sirus, Awakener of Worlds in cheap Path of exile currency the Atlas. Consider yourself rich though if one drops, or if you can farm Sirus consistently enough.
The Wall